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Pd(ii)-catalyzed synthesis of bifunctionalized carboranes via cage B–H activation of 1-CH(2)NH(2)-o-carboranes

Aminoalkyl carboranes are anticipated to be valuable synthons toward the synthesis of bifunctionalized carboranes. However, direct cage boron derivation of these carborane derivatives has not been solved. Herein, the reversible conversion of catalytically infeasible o-carboranyl methylamines (1-CH(2...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Zhang, Xiaolei, Yan, Hong
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5941203/
https://ncbi.nlm.nih.gov/pubmed/29780529
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc01154k
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