Spectroscopic investigations of a semi-synthetic [FeFe] hydrogenase with propane di-selenol as bridging ligand in the binuclear subsite: comparison to the wild type and propane di-thiol variants

[FeFe] Hydrogenases catalyze the reversible conversion of H(2) into electrons and protons. Their catalytic site, the H-cluster, contains a generic [4Fe–4S](H) cluster coupled to a [2Fe](H) subsite [Fe(2)(ADT)(CO)(3)(CN)(2)](2−), ADT = µ(SCH(2))(2)NH. Heterologously expressed [FeFe] hydrogenases (apo...

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Enregistré dans:
Détails bibliographiques
Publié dans:J Biol Inorg Chem
Auteurs principaux: Sommer, C., Rumpel, S., Roy, S., Farès, C., Artero, V., Fontecave, M., Reijerse, E., Lubitz, W.
Format: Artigo
Langue:Inglês
Publié: Springer Berlin Heidelberg 2018
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Original Paper
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC5940705/
https://ncbi.nlm.nih.gov/pubmed/29627860
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s00775-018-1558-4
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