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Room temperature olefination of methane with titanium–carbon multiple bonds
C–H activation of methane followed by dehydrocoupling at room temperature led ultimately to the formation of the olefin H(2)C[double bond, length as m-dash]CH(t)Bu via the addition of redox-active ligands (L) such as thioxanthone or 2,2′-bipyridine (bipy) to (PNP)Ti[double bond, length as m-dash]CH(...
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| Pubblicato in: | Chem Sci |
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| Autori principali: | , , , , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
Royal Society of Chemistry
2018
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5933228/ https://ncbi.nlm.nih.gov/pubmed/29780468 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc05238c |
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