Structural Modulation of Chromic Response: Effects of Binding‐Site Blocking in a Conjugated Calix[4]pyrrole Chromophore

Herein, we modulate the chromic response of a highly colored tetrapyrrole macrocycle, namely, tetrakis(3,5‐di‐tert‐butyl‐4‐oxocyclohexadien‐2,5‐yl)porphyrinogen (OxP) by structural modification. N‐Benzylation at the macrocyclic nitrogen atoms leads to stepwise elimination of the two calix[4]pyrrole‐...

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Publicat a:ChemistryOpen
Autors principals: Březina, Václav, Ishihara, Shinsuke, Lang, Jan, Hanyková, Lenka, Ariga, Katsuhiko, Hill, Jonathan P., Labuta, Jan
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2018
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5931546/
https://ncbi.nlm.nih.gov/pubmed/29744284
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/open.201800005
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