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NMR spectroscopic detection of chirality and enantiopurity in referenced systems without formation of diastereomers

Enantiomeric excess of chiral compounds is a key parameter that determines their activity or therapeutic action. The current paradigm for rapid measurement of enantiomeric excess using NMR is based on the formation of diastereomeric complexes between the chiral analyte and a chiral resolving agent,...

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Detalhes bibliográficos
Main Authors: Labuta, Jan, Ishihara, Shinsuke, Šikorský, Tomáš, Futera, Zdeněk, Shundo, Atsuomi, Hanyková, Lenka, Burda, Jaroslav V., Ariga, Katsuhiko, Hill, Jonathan P.
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Pub. Group 2013
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3759048/
https://ncbi.nlm.nih.gov/pubmed/23864041
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/ncomms3188
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