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Enantioselective γ-C(sp(3))–H Activation of Alkyl Amines via Pd(II)/Pd(0) Catalysis
Pd(II)-catalyzed enantioselective γ-C(sp(3))–H cross-coupling of alkyl amines via desymmetrization and kinetic resolution has been realized for the first time using chiral acetyl-protected aminomethyl oxazoline ligands (APAO). A diverse range of aryl- and vinyl-boron reagents can be used as coupling...
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| Publicado no: | J Am Chem Soc |
|---|---|
| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5927623/ https://ncbi.nlm.nih.gov/pubmed/29629766 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b01094 |
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