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Enantioselective γ-C(sp(3))–H Activation of Alkyl Amines via Pd(II)/Pd(0) Catalysis

Pd(II)-catalyzed enantioselective γ-C(sp(3))–H cross-coupling of alkyl amines via desymmetrization and kinetic resolution has been realized for the first time using chiral acetyl-protected aminomethyl oxazoline ligands (APAO). A diverse range of aryl- and vinyl-boron reagents can be used as coupling...

詳細記述

保存先:
書誌詳細
出版年:J Am Chem Soc
主要な著者: Shao, Qian, Wu, Qing-Feng, He, Jian, Yu, Jin-Quan
フォーマット: Artigo
言語:Inglês
出版事項: 2018
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC5927623/
https://ncbi.nlm.nih.gov/pubmed/29629766
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b01094
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