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Copper-catalyzed formylation of alkenyl C–H bonds using BrCHCl(2) as a stoichiometric formylating reagent

The first example of copper-catalyzed direct formylation of alkenyl C–H bonds for the facile synthesis of α,β-unsaturated aldehydes has been developed. This transformation has demonstrated high reactivity, mild reaction conditions and a broad substrate scope. BrCHCl(2) is expected to be developed as...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Bao, Yan, Wang, Gao-Yin, Zhang, Ya-Xuan, Bian, Kang-Jie, Wang, Xi-Sheng
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5915796/
https://ncbi.nlm.nih.gov/pubmed/29732081
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc00210j
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