Cooperative catalytic methoxycarbonylation of alkenes: uncovering the role of palladium complexes with hemilabile ligands

Mechanistic studies of the catalyst [Pd(2)(dba)(3)/1,1′-bis(tert-butyl(pyridin-2-yl)phosphanyl)ferrocene, L2] for olefin alkoxycarbonylation reactions are described. X-ray crystallography reveals the coordination of the pyridyl nitrogen atom in L2 to the palladium center of the catalytic intermediat...

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Bibliografiske detaljer
Udgivet i:Chem Sci
Main Authors: Dong, Kaiwu, Sang, Rui, Wei, Zhihong, Liu, Jie, Dühren, Ricarda, Spannenberg, Anke, Jiao, Haijun, Neumann, Helfried, Jackstell, Ralf, Franke, Robert, Beller, Matthias
Format: Artigo
Sprog:Inglês
Udgivet: Royal Society of Chemistry 2018
Fag:
Chemistry
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5912013/
https://ncbi.nlm.nih.gov/pubmed/29732128
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc02964k
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