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Catalytic vinylogous cross-coupling reactions of rhenium vinylcarbenoids

We report the first example of the rhenium-catalyzed allylation reaction of indolyl compounds by means of cross-coupling with propargyl ethers as non-obvious allylating reagents. Data from isotope-labeling and kinetic isotopic studies are consistent with a mechanism that proceeds by vinylidene forma...

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Détails bibliographiques
Publié dans:Chem Sci
Auteurs principaux: Chen, Ji, Wu, Jimmy
Format: Artigo
Langue:Inglês
Publié: Royal Society of Chemistry 2018
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC5909671/
https://ncbi.nlm.nih.gov/pubmed/29732125
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc05477g
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