Direct catalytic cross-coupling of alkenyllithium compounds

A catalytic method for the direct cross-coupling of alkenyllithium reagents with aryl and alkenyl halides is described. The use of a catalyst comprising Pd(2)(dba)(3)/XPhos allows for the stereoselective preparation of a wide variety of substituted alkenes in high yields under mild conditions. In ad...

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Bibliographic Details
Published in:Chem Sci
Main Authors: Hornillos, Valentín, Giannerini, Massimo, Vila, Carlos, Fañanás-Mastral, Martín, Feringa, Ben L.
Format: Artigo
Language:Inglês
Published: Royal Society of Chemistry 2015
Subjects:
Chemistry
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5811103/
https://ncbi.nlm.nih.gov/pubmed/29560227
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc03117b
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