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Exploiting exciton coupling of ligand radical intervalence charge transfer transitions to tune NIR absorption
We detail the rational design of a series of bimetallic bis-ligand radical Ni salen complexes in which the relative orientation of the ligand radical chromophores provides a mechanism to tune the energy of intense intervalence charge transfer (IVCT) bands in the near infrared (NIR) region. Through a...
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| Publicat a: | Chem Sci |
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| Autors principals: | , , , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
Royal Society of Chemistry
2017
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5887452/ https://ncbi.nlm.nih.gov/pubmed/29675206 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc04537a |
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