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Exploiting exciton coupling of ligand radical intervalence charge transfer transitions to tune NIR absorption

We detail the rational design of a series of bimetallic bis-ligand radical Ni salen complexes in which the relative orientation of the ligand radical chromophores provides a mechanism to tune the energy of intense intervalence charge transfer (IVCT) bands in the near infrared (NIR) region. Through a...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Clarke, Ryan M., Jeen, Tiffany, Rigo, Serena, Thompson, John R., Kaake, Loren G., Thomas, Fabrice, Storr, Tim
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5887452/
https://ncbi.nlm.nih.gov/pubmed/29675206
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc04537a
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