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Exploring the mechanism of the Pd-catalyzed spirocyclization reaction: a combined DFT and experimental study
The mechanism of the palladium-catalyzed spirocyclization of acrylamides has been investigated by density functional theory and experimental studies. The results support a mechanistic pathway that proceeds via oxidative addition, intramolecular carbopalladation, C–H bond activation, and migratory in...
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| Veröffentlicht in: | Chem Sci |
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| Hauptverfasser: | , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
Royal Society of Chemistry
2017
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5885594/ https://ncbi.nlm.nih.gov/pubmed/29675193 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc04709f |
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