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Mechanistic insights on the Pd-catalyzed addition of C–X bonds across alkynes – a combined experimental and computational study
The Pd-catalyzed intramolecular addition of carbamoyl chlorides and aryl halides across alkynes is investigated by means of DFT calculations and mechanistic test experiments. The data suggest a mechanistic pathway that involves oxidative addition, alkyne insertion, cis → trans isomerization and redu...
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| Publicado en: | Chem Sci |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
Royal Society of Chemistry
2017
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5376711/ https://ncbi.nlm.nih.gov/pubmed/28451357 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc05001h |
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