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Giant exchange coupling and field-induced slow relaxation of magnetization in Gd(2)@C(79)N with a single-electron Gd–Gd bond
Magnetic properties of the azafullerene Gd(2)@C(79)N are studied by SQUID magnetometry. The effective exchange coupling constant j(Gd,e) between the Gd spins and the spin of unpaired electron residing on the single-electron Gd–Gd bond is determined to be 170 ± 10 cm(–1). Low temperature AC measureme...
Shranjeno v:
| izdano v: | Chem Commun (Camb) |
|---|---|
| Main Authors: | , , , , , , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
Royal Society of Chemistry
2018
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5885278/ https://ncbi.nlm.nih.gov/pubmed/29497728 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8cc00112j |
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