High Blocking Temperature of Magnetization and Giant Coercivity in the Azafullerene Tb(2)@C(79)N with a Single‐Electron Terbium–Terbium Bond

The azafullerene Tb(2)@C(79)N is found to be a single‐molecule magnet with a high 100‐s blocking temperature of magnetization of 24 K and large coercivity. Tb magnetic moments with an easy‐axis single‐ion magnetic anisotropy are strongly coupled by the unpaired spin of the single‐electron Tb−Tb bond...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Velkos, Georgios, Krylov, Denis S., Kirkpatrick, Kyle, Spree, Lukas, Dubrovin, Vasilii, Büchner, Bernd, Avdoshenko, Stanislav M., Bezmelnitsyn, Valeriy, Davis, Sean, Faust, Paul, Duchamp, James, Dorn, Harry C., Popov, Alexey A.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2019
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6519270/
https://ncbi.nlm.nih.gov/pubmed/30786125
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201900943
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