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Rapid access to the core skeleton of the [3 + 2]-type dimeric pyrrole–imidazole alkaloids by triplet ketone-mediated C–H functionalization
The ability of triplet ketones to abstract a hydrogen atom from hydrocarbons is reminiscent of that of the high-spin metal-oxo complexes in C–H oxidation enzymes. In practice, the reactivity of triplet ketones is easier to control and applicable to promoting a wider range of reactions. We demonstrat...
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| Publicado no: | Tetrahedron |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5880548/ https://ncbi.nlm.nih.gov/pubmed/29622843 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2017.12.027 |
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