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Configurational Analysis of Tetracyclic Dimeric Pyrrole-Imidazole Alkaloids using a Floating Chirality Approach

The structure elucidation of the palau'amine congener tetrabromostyloguanidine (1), which used interproton distances from ROESY spectra as restraints in a computational approach, the so-called fc-rDG/DDD method, led to a revision of the relative configuration of palau'amine (2) and its con...

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Detalhes bibliográficos
Main Authors: Köck, Matthias, Schmidt, Gesine, Seiple, Ian B., Baran, Phil S.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3315375/
https://ncbi.nlm.nih.gov/pubmed/22332969
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/np200514g
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