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Stereoselective construction of sterically hindered oxaspirocycles via chiral bidentate directing group-mediated C(sp(3))–O bond formation
The systematic investigation of chiral bidentate auxiliaries has resulted in the discovery of a chiral 2,2-dimethyl-1-(pyridin-2-yl)propan-1-amine-derived directing group that enables stereoselective palladium(ii)-catalyzed intramolecular C(sp(3))–O bond formation. This new chiral directing group ex...
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Publicado no: | Chem Sci |
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Main Authors: | , , , , , , |
Formato: | Artigo |
Idioma: | Inglês |
Publicado em: |
Royal Society of Chemistry
2017
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Assuntos: | |
Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5875089/ https://ncbi.nlm.nih.gov/pubmed/29629170 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc04691j |
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