Rh(iii)-catalyzed regioselective intermolecular N-methylene Csp(3)–H bond carbenoid insertion

A Rh(iii)-catalyzed regioselective intermolecular carbenoid insertion into the N-methylene Csp(3)–H bond of acyclic aliphatic amides has been achieved, taking advantage of bidentate–chelation assistance. This methodology has been successfully applied to a broad range of linear and branched-chain N-a...

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Bibliographic Details
Published in:Chem Sci
Main Authors: Xie, Haisheng, Ye, Zongren, Ke, Zhuofeng, Lan, Jianyong, Jiang, Huanfeng, Zeng, Wei
Format: Artigo
Language:Inglês
Published: Royal Society of Chemistry 2017
Subjects:
Chemistry
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5874982/
https://ncbi.nlm.nih.gov/pubmed/29629165
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc03802j
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