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Cobalt-catalyzed regioselective stereoconvergent Markovnikov 1,2-hydrosilylation of conjugated dienes

We report the first stereoconvergent Markovnikov 1,2-hydrosilylation of conjugated dienes using catalysts generated from bench-stable Co(acac)(2) and phosphine ligands. A wide range of E/Z-dienes underwent this Markovnikov 1,2-hydrosilylation in a stereoconvergent manner, affording (E)-allylsilanes...

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Bibliografische gegevens
Gepubliceerd in:Chem Sci
Hoofdauteurs: Sang, Hui Leng, Yu, Songjie, Ge, Shaozhong
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: Royal Society of Chemistry 2017
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Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5873224/
https://ncbi.nlm.nih.gov/pubmed/29629163
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc04002d
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