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Synthesis of the Privileged 8-Arylmenthol Class by Radical Arylation of Isopulegol
Hydrogen atom transfer (HAT) circumvents a disfavored Friedel-Crafts reaction in the derivatization of the inexpensive monoterpene isopulegol. A variety of readily-prepared aryl and heteroaryl sulfonates undergo a formal hydroarylation to form 8-arylmenthols, privileged scaffolds for asymmetric synt...
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| Publicado no: | Org Lett |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5871529/ https://ncbi.nlm.nih.gov/pubmed/27175746 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.6b01047 |
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