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Spontaneous (15)N Nuclear Spin Hyperpolarization in Metal-Free Activation of Parahydrogen by Molecular Tweezers

[Image: see text] The ability of frustrated Lewis pairs (FLPs) to activate H(2) is of significant interest for metal-free catalysis. The activation of H(2) is also the key element of parahydrogen-induced polarization (PHIP), one of the nuclear spin hyperpolarization techniques. It is demonstrated th...

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Bibliografske podrobnosti
izdano v:J Phys Chem Lett
Main Authors: Sorochkina, Kristina, Zhivonitko, Vladimir V., Chernichenko, Konstantin, Telkki, Ville-Veikko, Repo, Timo, Koptyug, Igor V.
Format: Artigo
Jezik:Inglês
Izdano: American Chemical Society 2018
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC5862329/
https://ncbi.nlm.nih.gov/pubmed/29401399
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpclett.7b03433
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