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Parahydrogen-induced polarization with a metal-free P–P biradicaloid
Metal-free H(2) activations are unusual but interesting for catalytic transformations, particularly in parahydrogen-based nuclear spin hyperpolarization techniques. We demonstrate that metal-free singlet phosphorus biradicaloid, [P(μ-NTer)](2), provides pronounced (1)H and (31)P hyperpolarization wh...
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| izdano v: | Phys Chem Chem Phys |
|---|---|
| Main Authors: | , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
Royal Society of Chemistry
2019
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6430094/ https://ncbi.nlm.nih.gov/pubmed/30694276 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8cp07625a |
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