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Bioinspired synthesis of pentacyclic onocerane triterpenoids
The first chemical synthesis of pentacyclic onocerane triterpenoids has been achieved. A putative biomimetic tricyclization cascade is employed to forge a fused decalin-/oxepane ring system. The synthetic route proceeds to (+)-cupacinoxepin in seven steps and to (+)-onoceranoxide in eight steps in t...
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| Publicat a: | Chem Sci |
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| Autors principals: | , , , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
Royal Society of Chemistry
2017
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5858022/ https://ncbi.nlm.nih.gov/pubmed/29619174 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc03903d |
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