Catalytic 1,2-dihydronaphthalene and E-aryl-diene synthesis via Co(III)–Carbene radical and o-quinodimethane intermediates

Catalytic synthesis of substituted 1,2-dihydronaphthalenes via metalloradical activation of o-styryl N-tosyl hydrazones ((E)-2-(prop-1-en-1-yl)benzene-N-tosyl hydrazones) is presented, taking advantage of the intrinsic reactivity of a cobalt(iii)–carbene radical intermediate. The method has been suc...

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Publicado en:Chem Sci
Autores principales: te Grotenhuis, Colet, Das, Braja G., Kuijpers, Petrus F., Hageman, Wouter, Trouwborst, Mees, de Bruin, Bas
Formato: Artigo
Lenguaje:Inglês
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC5857932/
https://ncbi.nlm.nih.gov/pubmed/29568470
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc03909c
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