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Catalysis with chalcogen bonds: neutral benzodiselenazole scaffolds with high-precision selenium donors of variable strength

The benzodiselenazoles (BDS) introduced in this report fulfill, for the first time, all the prerequisites for non-covalent high-precision chalcogen-bonding catalysis in the focal point of conformationally immobilized σ holes on strong selenium donors in a neutral scaffold. Rational bite-angle adjust...

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Détails bibliographiques
Publié dans:Chem Sci
Auteurs principaux: Benz, Sebastian, Mareda, Jiri, Besnard, Céline, Sakai, Naomi, Matile, Stefan
Format: Artigo
Langue:Inglês
Publié: Royal Society of Chemistry 2017
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC5855965/
https://ncbi.nlm.nih.gov/pubmed/29568463
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc03866f
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