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Phosphate-Catalyzed Succinimide Formation from Asp Residues: A Computational Study of the Mechanism

Aspartic acid (Asp) residues in proteins and peptides are prone to the non-enzymatic reactions that give biologically uncommon l-β-Asp, d-Asp, and d-β-Asp residues via the cyclic succinimide intermediate (aminosuccinyl residue, Suc). These abnormal Asp residues are known to have relevance to aging a...

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Veröffentlicht in:Int J Mol Sci
Hauptverfasser: Kirikoshi, Ryota, Manabe, Noriyoshi, Takahashi, Ohgi
Format: Artigo
Sprache:Inglês
Veröffentlicht: MDPI 2018
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Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5855859/
https://ncbi.nlm.nih.gov/pubmed/29495268
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/ijms19020637
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