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Structure-guided reprogramming of a hydroxylase to halogenate its small molecule substrate
Enzymatic installation of chlorine/bromine upon unactivated carbon centers provides a versatile, selective, and environmentally-friendly alternative to chemical halogenation. Iron(II)- and 2-(oxo)-glutarate (Fe(II)/2OG)-dependent halogenases are powerful biocatalysts that are capable of cleaving ali...
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| Publicado no: | Biochemistry |
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| Main Authors: | , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5852377/ https://ncbi.nlm.nih.gov/pubmed/28029241 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.biochem.6b01173 |
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