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Ligand-Enabled γ-C(sp(3))–H Activation of Ketones
We report the first example of Pd(II)-catalyzed γ-C(sp(3))–H activation of ketones directed by a practical 2,2-dimethyl aminooxyacetic acid auxiliary. 2-Pyridone ligands are identified to enable C(sp(3))–H activation for the first time. A rare six-membered palladacycle intermediate was isolated and...
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| Publicat a: | J Am Chem Soc |
|---|---|
| Autors principals: | , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2018
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5851877/ https://ncbi.nlm.nih.gov/pubmed/29481072 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b01359 |
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