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Anion Relay Chemistry: Development of an Effective Diastereoselective [3+2] Annulation Tactic Exploiting an Aldol/Brook Rearrangement/Cyclization Cascade
An effective [3+2] annulation tactic for the construction of diverse bicyclic compounds possessing highly functionalized cyclopentane rings has been developed employing soft ketone enolates as the initial nucleophile for Anion-Relay-Chemistry (ARC). The protocol entails a highly diastereoselective A...
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| Yayımlandı: | Angew Chem Int Ed Engl |
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| Asıl Yazarlar: | , |
| Materyal Türü: | Artigo |
| Dil: | Inglês |
| Baskı/Yayın Bilgisi: |
2017
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| Konular: | |
| Online Erişim: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5836311/ https://ncbi.nlm.nih.gov/pubmed/29024282 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201708017 |
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