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Type II Anion Relay Chemistry: Conformational Constraints To Achieve Effective [1,5]-Vinyl Brook Rearrangements

The design, synthesis, and evaluation of bifunctional linchpins, conformationally anchored on six-membered rings to achieve efficient [1,5]-Brook rearrangements involving vinyl silanes have been achieved. The restrained linchpins were subsequently exploited in type II anion relay chemistry (ARC) to...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Liu, Qi, Chen, Yu, Zhang, Xiao, Houk, K. N., Liang, Yong, Smith, Amos B.
Formato: Artigo
Idioma:Inglês
Publicado em: 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5558205/
https://ncbi.nlm.nih.gov/pubmed/28613847
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b04149
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