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High-Spin Iron Imido Complexes Competent for C–H Bond Amination
Reduction of previously reported ((Ar)L)FeCl with potassium graphite furnished a low-spin (S = 1/2) iron complex ((Ar)L)Fe which features an intramolecular η(6)-arene interaction and can be utilized as an Fe(I) synthon ((Ar)L = 5-mesityl-1,9-(2,4,6-Ph(3)C(6)H(2))dipyrrin). Treatment of ((Ar)L)Fe wit...
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| Pubblicato in: | J Am Chem Soc |
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| Autori principali: | , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2017
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5821117/ https://ncbi.nlm.nih.gov/pubmed/28777558 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b06682 |
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