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Critical analysis of the limitations of Bleaney's theory of magnetic anisotropy in paramagnetic lanthanide coordination complexes

The origins of the breakdown of Bleaney's theory of magnetic anisotropy are described, based on an analysis of eleven different complexes of the second half of the 4f elements that form isostructural series. An examination of the chemical shift and relaxation rate behaviour of resonances locate...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Funk, Alexander M., Finney, Katie-Louise N. A., Harvey, Peter, Kenwright, Alan M., Neil, Emily R., Rogers, Nicola J., Kanthi Senanayake, P., Parker, David
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5812375/
https://ncbi.nlm.nih.gov/pubmed/29449916
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc03429e
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