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Asymmetric Lewis acid catalysis directed by octahedral rhodium centrochirality
A rhodium-based asymmetric catalyst is introduced which derives its optical activity from octahedral centrochirality. Besides providing the exclusive source of chirality, the rhodium center serves as a Lewis acid by activating 2-acyl imidazoles through two point binding and enabling a very effective...
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| Publicado no: | Chem Sci |
|---|---|
| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5811158/ https://ncbi.nlm.nih.gov/pubmed/29560197 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc03101f |
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