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What is the trigger mechanism for the reversal of electron flow in oxygen-tolerant [NiFe] hydrogenases?
The [NiFe] hydrogenases use an electron transfer relay of three FeS clusters – proximal, medial and distal – to release the electrons from the principal reaction, H(2) → 2H(+) + 2e(–), that occurs at the Ni–Fe catalytic site. This site is normally inactivated by O(2), but the subclass of O(2)-tolera...
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| Publicado no: | Chem Sci |
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| Autor principal: | |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5811149/ https://ncbi.nlm.nih.gov/pubmed/29560232 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc03223c |
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