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P–N Cooperative Borane Activation and Catalytic Hydroboration by a Distorted Phosphorous Triamide Platform

Studies on the stoichiometric and catalytic reactivity of a geometrically constrained phosphorous triamide 1 with pinacolborane (HBpin) are reported. The addition of HBpin to phosphorous triamide 1 results in cleavage of the B-H bond of pinacolborane through addition across electrophilic phosphorus...

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Foilsithe in:J Am Chem Soc
Main Authors: Lin, Yi-Chun, Hatzakis, Emmanuel, McCarthy, Sean M., Reichl, Kyle D., Lai, Ting-Yi, Yennawar, Hemant P., Radosevich, Alexander T.
Formáid: Artigo
Teanga:Inglês
Foilsithe: 2017
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC5778438/
https://ncbi.nlm.nih.gov/pubmed/28398750
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b02512
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