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Hydrodecarboxylation of Carboxylic and Malonic Acid Derivatives via Organic Photoredox Catalysis: Substrate Scope and Mechanistic Insight

A direct, catalytic hydrodecarboxylation of primary, secondary, and tertiary carboxylic acids is reported. The catalytic system consists of a Fukuzumi acridinium photooxidant with phenyldisulfide acting as a redox-active cocatalyst. Substoichiometric quantities of Hünig’s base are used to reveal the...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Griffin, Jeremy D., Zeller, Mary A., Nicewicz, David A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5768415/
https://ncbi.nlm.nih.gov/pubmed/26291730
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b07770
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