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Magnesium Boryl Reactivity with 9‐BBN and Ph(3)B: Rational B−B′ Bond Formation and Diborane Isomerization
Reactions of a magnesium‐based pinacolatoboryl nucleophile with the electrophilic organoboranes, 9‐BBN and Ph(3)B, provide facile B−B′ single bond formation. Although the Ph(3)B derivative is thermally stable, when heated, the unsymmetrical diborane(5) anion derived from 9‐BBN is found to isomerize...
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| Publicado en: | Angew Chem Int Ed Engl |
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| Autores principales: | , , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
John Wiley and Sons Inc.
2017
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5767756/ https://ncbi.nlm.nih.gov/pubmed/29115736 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201709902 |
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