Catalytic Dibenzocyclooctene Synthesis via Cobalt(III)–Carbene Radical and ortho‐Quinodimethane Intermediates

The metalloradical activation of ortho‐benzallylaryl N‐tosyl hydrazones with [Co(TPP)] (TPP=tetraphenylporphyrin) as the catalyst enabled the controlled exploitation of the single‐electron reactivity of the redox non‐innocent carbene intermediate. This method offers a novel route to prepare eight‐me...

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Publicado en:Angew Chem Int Ed Engl
Autores principales: te Grotenhuis, Colet, van den Heuvel, Naudin, van der Vlugt, Jarl Ivar, de Bruin, Bas
Formato: Artigo
Lenguaje:Inglês
Publicado: John Wiley and Sons Inc. 2017
Materias:
Communications
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC5767734/
https://ncbi.nlm.nih.gov/pubmed/29155465
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201711028
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