Electrocatalytic Azide Oxidation Mediated by a Rh(PNP) Pincer Complex

One‐electron oxidation of the rhodium(I) azido complex [Rh(N(3))(PNP)] (5), bearing the neutral, pyridine‐based PNP ligand 2,6‐bis(di‐tert‐butylphosphinomethyl)pyridine, leads to instantaneous and selective formation of the mononuclear rhodium(I) dinitrogen complex [Rh(N(2))(PNP)](+) (9 (+)). Intere...

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Publicat a:Chemistry
Autors principals: Rebreyend, Christophe, Gloaguen, Yann, Lutz, Martin, van der Vlugt, Jarl Ivar, Siewert, Inke, Schneider, Sven, de Bruin, Bas
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2017
Matèries:
Communications
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5765409/
https://ncbi.nlm.nih.gov/pubmed/28898478
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201702938
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