Photoinduced Carboborative Ring Contraction Enables Regio- and Stereoselective Synthesis of Multiply Substituted Five-Membered Carbocycles and Heterocycles

We report herein a photoinduced carboborative ring contraction of monounsaturated six-membered carbocycles and heterocycles. The reaction produces substituted five-membered ring systems stereoselectively and on preparative scales. The products feature multiple stereocenters, including contiguous qua...

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Vydáno v:J Am Chem Soc
Hlavní autoři: Jin, Shengfei, Nguyen, Vu T., Dang, Hang T., Nguyen, Dat P., Arman, Hadi D., Larionov, Oleg V.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2017
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5737778/
https://ncbi.nlm.nih.gov/pubmed/28780859
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b07128
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