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Halide Control of N,N-Coordination versus N,C-Cyclometalation and Stereospecific Phenyl Ring Deuteration of Osmium(II) p-Cymene Phenylazobenzothiazole Complexes
[Image: see text] We report the synthesis of halido Os(II) p-cymene complexes bearing bidentate chelating phenylazobenzothiazole (AZBTZ) ligands. Unlike the analogous phenylazopyridine (AZPY) complexes, AZBTZ-NMe(2) is capable of both N,N-coordination to Os(II) and cyclometalation to form N,C-coordi...
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| Publicado no: | Organometallics |
|---|---|
| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical Society
2017
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5726741/ https://ncbi.nlm.nih.gov/pubmed/29249848 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.organomet.7b00501 |
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