Halide Control of N,N-Coordination versus N,C-Cyclometalation and Stereospecific Phenyl Ring Deuteration of Osmium(II) p-Cymene Phenylazobenzothiazole Complexes

[Image: see text] We report the synthesis of halido Os(II) p-cymene complexes bearing bidentate chelating phenylazobenzothiazole (AZBTZ) ligands. Unlike the analogous phenylazopyridine (AZPY) complexes, AZBTZ-NMe(2) is capable of both N,N-coordination to Os(II) and cyclometalation to form N,C-coordi...

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Bibliographic Details
Published in:Organometallics
Main Authors: Needham, Russell J., Habtemariam, Abraha, Barry, Nicolas P. E., Clarkson, Guy, Sadler, Peter J.
Format: Artigo
Language:Inglês
Published: American Chemical Society 2017
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5726741/
https://ncbi.nlm.nih.gov/pubmed/29249848
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.organomet.7b00501
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