A Computational Investigation of the Ligand-Controlled Cu-Catalyzed Site-Selective Propargylation and Allenylation of Carbonyl Compounds

[Image: see text] A copper-catalyzed site-selective propargylation/allenylation reaction toward carbonyl compounds has been mechanistically investigated using a computational approach. Different reaction pathways and catalytic cycles were investigated. Control of the site selectivity arises from a d...

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Publicat a:Org Lett
Autors principals: Zou, Yike, Gutierrez, Osvaldo, Sader, Avery C., Patel, Nitinchandra D., Fandrick, Daniel R., Busacca, Carl A., Fandrick, Keith R., Kozlowski, Marisa, Senanayake, Chris H.
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2017
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5718194/
https://ncbi.nlm.nih.gov/pubmed/29095633
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.7b02845
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