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Effect of H bond removal and changes in the position of the iron–sulphur head domain on the spin–lattice relaxation properties of the [2Fe–2S](2+) Rieske cluster in cytochrome bc(1)
Here, comparative electron spin–lattice relaxation studies of the 2Fe–2S iron–sulphur (Fe–S) cluster embedded in a large membrane protein complex – cytochrome bc(1) – are reported. Structural modifications of the local environment alone (mutations S158A and Y160W removing specific H bonds between Fe...
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| Publicado en: | Phys Chem Chem Phys |
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| Autores principales: | , , , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
Royal Society of Chemistry
2015
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5716461/ https://ncbi.nlm.nih.gov/pubmed/26355649 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5cp02815a |
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