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Distinct properties of semiquinone species detected at the ubiquinol oxidation Q(o) site of cytochrome bc(1) and their mechanistic implications

The two-electron ubiquinol oxidation or ubiquinone reduction typically involves semiquinone (SQ) intermediates. Natural engineering of ubiquinone binding sites of bioenergetic enzymes secures that SQ is sufficiently stabilized, so that it does not leave the site to membranous environment before full...

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Veröffentlicht in:J R Soc Interface
Hauptverfasser: Pietras, Rafał, Sarewicz, Marcin, Osyczka, Artur
Format: Artigo
Sprache:Inglês
Veröffentlicht: The Royal Society 2016
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Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4892266/
https://ncbi.nlm.nih.gov/pubmed/27194483
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1098/rsif.2016.0133
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