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Distinct properties of semiquinone species detected at the ubiquinol oxidation Q(o) site of cytochrome bc(1) and their mechanistic implications

The two-electron ubiquinol oxidation or ubiquinone reduction typically involves semiquinone (SQ) intermediates. Natural engineering of ubiquinone binding sites of bioenergetic enzymes secures that SQ is sufficiently stabilized, so that it does not leave the site to membranous environment before full...

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Détails bibliographiques
Publié dans:J R Soc Interface
Auteurs principaux: Pietras, Rafał, Sarewicz, Marcin, Osyczka, Artur
Format: Artigo
Langue:Inglês
Publié: The Royal Society 2016
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC4892266/
https://ncbi.nlm.nih.gov/pubmed/27194483
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1098/rsif.2016.0133
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