Assessing the exchange coupling in binuclear lanthanide(iii) complexes and the slow relaxation of the magnetization in the antiferromagnetically coupled Dy(2) derivative

We report here the synthesis and the investigation of the magnetic properties of a series of binuclear lanthanide complexes belonging to the metallacrown family. The isostructural complexes have a core structure with the general formula [Ga(4)Ln(2)(shi(3–))(4)(Hshi(2–))(2)(H(2)shi(–))(2)(C(5)H(5)N)(...

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Udgivet i:Chem Sci
Main Authors: Chow, Chun Y., Bolvin, Hélène, Campbell, Victoria E., Guillot, Régis, Kampf, Jeff W., Wernsdorfer, Wolfgang, Gendron, Frédéric, Autschbach, Jochen, Pecoraro, Vincent L., Mallah, Talal
Format: Artigo
Sprog:Inglês
Udgivet: Royal Society of Chemistry 2015
Fag:
Chemistry
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5707489/
https://ncbi.nlm.nih.gov/pubmed/29218180
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc01029b
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