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Assessing the exchange coupling in binuclear lanthanide(iii) complexes and the slow relaxation of the magnetization in the antiferromagnetically coupled Dy(2) derivative

We report here the synthesis and the investigation of the magnetic properties of a series of binuclear lanthanide complexes belonging to the metallacrown family. The isostructural complexes have a core structure with the general formula [Ga(4)Ln(2)(shi(3–))(4)(Hshi(2–))(2)(H(2)shi(–))(2)(C(5)H(5)N)(...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Chow, Chun Y., Bolvin, Hélène, Campbell, Victoria E., Guillot, Régis, Kampf, Jeff W., Wernsdorfer, Wolfgang, Gendron, Frédéric, Autschbach, Jochen, Pecoraro, Vincent L., Mallah, Talal
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5707489/
https://ncbi.nlm.nih.gov/pubmed/29218180
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc01029b
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