Organocatalytic asymmetric chlorinative dearomatization of naphthols

An organocatalytic asymmetric chlorinative dearomatization of naphthols was realized for the first time, providing chiral naphthalenones with a Cl-containing all-substituted stereocenter in excellent yields and enantioselectivity (up to 97% yield and 96% ee). The reaction features mild reaction cond...

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Bibliographic Details
Published in:Chem Sci
Main Authors: Yin, Qin, Wang, Shou-Guo, Liang, Xiao-Wei, Gao, De-Wei, Zheng, Jun, You, Shu-Li
Format: Artigo
Language:Inglês
Published: Royal Society of Chemistry 2015
Subjects:
Chemistry
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5707459/
https://ncbi.nlm.nih.gov/pubmed/29218183
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc00494b
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