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Controlling Regioselectivity in the Enantioselective N-Alkylation of Indole Analogs Catalyzed by Dinuclear Zinc-ProPhenol

The enantioselective N-alkylation of indole and its derivatives with aldimines is efficiently catalyzed by a zinc-ProPhenol dinuclear complex under mild conditions to afford N-alkylated indole derivatives in good yield (up to 86%) and excellent enantiomeric ratio (up to 99.5: 0.5 e.r.). This protoco...

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Publicado en:Angew Chem Int Ed Engl
Main Authors: Trost, Barry M., Gnanamani, Elumalai, Hung, Chao-I (Joey)
Formato: Artigo
Idioma:Inglês
Publicado: 2017
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC5706662/
https://ncbi.nlm.nih.gov/pubmed/28654735
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201705315
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